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In [60]: s.plot(kind='bar', align='center')
Out[60]: <matplotlib.axes.AxesSubplot at 0xc1f3810>
In [61]: ax = gca()
In [62]: ax2 = twinx(ax)
In [63]: s.plot(ax=ax2)
Out[63]: <matplotlib.axes.AxesSubplot at 0xd1ffc50>